Geochemical Characteristics of Limestone of Wonosari-Punung Formation, Gunungkidul Regency, Yogyakarta, Indonesia

Didik Dwi Atmoko, Anastasia Dewi Titisari, Arifudin Idrus


DOI: 10.17014/ijog.5.2.179-197A geochemical study was carried out to determine the geochemical characteristics of limestone in Wonosari-Punung Formation, and to suggest its depositional conditions and the source of rare earth elements. The study was conducted at Ponjong Area, Gunungkidul Regency, Daerah Istimewa Yogyakarta, Indonesia. White limestone which contains more abundant calcite is characterized by the highest CaO concentration. Red limestone which is associated with impure minerals such as siderite, rodochrosite, hematite, and titanite is typified by depleted CaO but higher SiO2, Fe2O3, MnO, and TiO2 concentrations. Grey limestone characterized by depleted CaO and higher MnO contents is considered to be influenced by the presence of impure minerals of manganite (Mn2O3.H2O) and/or pyrolusite (MnO2). Depletion of Sr concentration in the coloured limestone indicates that the diagenetic process increases from the white limestone to the coloured limestone. The process possibly occurred post-deposition of the limestones. The limestones show positive Mn* values (2.46 - 2.95) and authigenic U values (0.89 - 3.38) that suggest an oxidative environment. The Ce/Ce* values (0.57 - 0.80), Eu/Eu* values (1.04 - 1.88), high Y/Ho ratio, and low LaN/YbN ratio are indications that the rare earth elements in the limestones were derived from terrigenous materials. The positive Eu anomaly and enrichment of Cr and Mn of the limestones are indications of hydrothermal fluid activity taking place in the studied area. Based on the geochemical characteristics of the Punung-Wonosari limestones, the depositional environment and the source of rare earth elements of the limestones were therefore influenced by a combination of hydrothermal fluid activity with small amount of terrigenous material input and post depositional diagenetic process.


diagenetic process; rare earth elements; trace elements; oxidative condition; source of rare earth elements


Atmoko, D. D., 2016. Depositional Environment and Mineral Controlling Red Limestone at Sawahan Area and surroundings, Ponjong Subdistrict, Gunungkidul District, Special Region of Yogyakarta (in Indonesian). S.T. Thesis, Unpublished, Gadjah Mada University, Yogyakarta, 144 pp.

Atmoko, D. D., Titisari, A. D., and Idrus, A., 2016. Mineralogy and Geochemistry of Ponjong Red Limestone, Gunungkidul, Daerah Istimewa Yogyakarta – Indonesia. RISET - Geologi dan Pertambangan. 26(1), 55-67. DOI:10.14203/risetgeotam2016.v26.269

Azizi, S. H. H., Shabestari, G. M. and Khazaei, A., 2014. Petrography and geochemistry of Paleocene–Eocene limestones in the Ching-dar syncline, eastern Iran. Geoscience Frontiers. 5, 429-438. DOI:10.1016/j.gsf.2013.08.002

Bau, M. and Dulski, P., 1996. Distribution of yttrium and rare earth elements in the Penge and Kuruman iron formation, Transvaal Supergroup, South Africa. Precambrian Research. 79, 37-55. DOI:10.1016/0301-9268(95)00087-9

Bellanca, A., Claps, M., Erba, E., Masetti, D., Neri, R., Premoli-Silva, I. and Venezia, F., 1996. Orbitally induced limestone/marlstone rhythms in the Albian-Cenomanian Cismon section (Venetian región, northern Italy): sedimentology, calcareous and siliceous plankton distribution, elemental and isotope geochemistry. Palaeogeography, Palaeoclimatology, Palaeoecology. 126, 227-260. DOI:10.1016/S0031-0182(96)00041-7

Berner, R.A., 1981. A new geochemical classification of sedimentary environments. Journal of Sedimentary Petrology, 51, p.359-365. DOI:10.1306/212F7C7F-2B24-11D7-8648000102C1865D

Bodine, M.W., Holland, H.D., and Boresik, M., 1965. Co-Precipitation of manganese and strontium with calcite. Symposium on problems of post magnetic ore deposition Praque, 11, p.401-406.

Bolhar, R., Kamber, B.S., Moorbath, S, Fedo, C.M. and Whitehouse, M.J., 2004. Characterisation of early Archaean chemical sediments by trace element signatures. Earth and Planetary Science Letters. 222, 43-60. DOI:10.1016/j.epsl.2004.02.016

Butuzova, G.Y., Drits, V.A., Morozov, A.A., and Gorschkov, A.I., 1990. Processes of formation of iron-manganese oxyhydroxides in the Atlantis-II and Thetis Deeps of the Red Sea. Sediment-Hosted Mineral Deposits: Proceedings of a Symposium Held in Beijing,People’s Republic of China, 11, p.57-72. DOI:10.1002/9781444303872.ch6

Chen, L., Lin, A.T.S., Da, X., Yi, H., Tsai, L.L.Y., and Xu, G., 2012. Sea-Level Changes Recorded by Cerium Anomalies in the Late Jurassic (Tithonian) Black Rocks Series of Qiangtang Basin, North-Central Tibet. Oil Shale. 29, p.18-35. DOI:10.3176/oil.2012.1.03

Chien, N.X., Khai, P.N., Hien, D.T., Nguyen, D., Bot, D.C., Trung, T.V., Cuc, N.T., Minh, L.H., Thuc, N.V., Ngan, B.T., and Thuan, D.V., 2006. The Determination of rare earth elements in Geological and environmental samples by Inductively Coupled Plasma Mass Spectrometry. Institute for Technology of Radioactive and Rare Element. The Annual Report for 2006, VAEC, VAEC-AR 06-31, p.217-225.

Condie, K.C., 1991. Another look at rare earth elements in shales. Geochimica et Cosmochimica Acta, 55 (9), p.2527-2531. DOI:10.1016/0016-7037(91)90370-K

Condie, K.C., Wilks, M., Rosen, D.M., and Zlobin, V.L., 1991. Geochemistry of metasediments from the Precambrian Hapschan series, eastern Anabar Shield, Siberia. Precambrian Research, 50 (1-2), p.37-47. DOI:10.1016/0301-9268(91)90046-D

Coope, J.A., Lavin, O.P., Weiland, E.F., and James, L.D., 1991. Exploration Geochemistry Short Course Manual?

Corbett, G.J. and Leach, T.M., 1997. Southwest Pacific Rim Gold-Copper Systems: Structure, Alteration, and Mineralization. Corbett Geological Services, 318pp.

Elderfield, H., 1988. The oceanic chemistry of the rare earth elements. Philosophical Transactions of the Royal Society of London. 325, 105-106. DOI:10.1098/rsta.1988.0046

Elderfield, H. and Greaves, M.J., 1982. The rare earth elements in seawater. Nature, 296, p.214-219. DOI:10.1038/296214a0

Embry, A.F. and Klovan, J.E., 1971. A Late Devonian Reef Tract on Northeastern Banks Island, NWT. Canadian Petroleum Geology Bulletin, 19, p.730-781.

German, C.R. and Elderfield, H., 1990. Application of Ce anomaly as a paleo redox indicator: the ground rules. Paleoceanography. 5, 823-833. DOI:10.1029/PA005i005p00823

German, C.R., Holliday, B.P., and Elderfield, H., 1993. A geochemical study of metalliferous sediment from the TAG hydrothermal mound, 26º08’ N, Mid-Atlantic ridge. Journal of Geophysical Research. 98, 9683-9692. DOI:10.1029/92JB01705

Holser, W.T., 1997. Evaluation of the application of rare earth elements to paleoceanography. Palaeogeography, Palaeoclimatology, Palaeoecology. 132, 309-323.

Jauhari, U. and Toha, B., 2005. High Resolution Sequence Stratigraphy and Diagenesis in Carbonate Rocks, Wonosari Formation, Yogyakarta: An Outcrop Analog for Modeling Chalky Limestone Reservoir Distribution. Proceedings of Indonesian Petroleum Association, 30th Annual Convention & Exhibition, August 2005. Indonesia.

Lawrence, M.G. and Kamber, B.S., 2006. The behaviour of the rare earth elements during estuarine mixing – revisited. Marine Chemistry. 100, 147-161.

Liu, Y.G., Miah, M.R.U. and Schmitt, R.A., 1988. Cerium: a chemical tracer for paleo-oceanic redox conditions. Geochimica et Cosmochimica Acta. 52, 1361-1371.

Lokier, S. W., 1999. The Development of the Miocene Wonosari Formation, South Central Java. Proceedings of Indonesian Petroleum Association, 27th Annual Convention & Exhibition. October 1999. Indonesia.

Machhour, L., Philip, J. and Oudin, J.L., 1994. Formation of laminate deposits in anaerobic-dysaerobic marine environments. Marine Geology. 117, 287-302.

MacRae, N.D., Nesbitt, H.W., and Kronberg, B.I., 1992. Development of a positive Eu anomaly during diagenesis. Earth and Planetary Science Letters. 109, 585-591. DOI:10.1016/0012-821X(92)90116-D

Madhavaraju, J. and González-León, C.M., 2012. Depositional conditions and source of rare earth elements in carbonate strata of the Aptian-Albian Mural Formation, Pitaycachi section, northeastern Sonora, Mexico. Revista Mexicana de Ciencias Geológicas. 29, 478-491.

Madhavaraju, J. and Lee, Y.I., 2009. Geochemistry of the Dalmiapuram Formation of the Uttatur Group (Early Cretaceous), Cauvery Basin, southeastern India: Implications on provenance and paleoredox conditions. Revista Mexicana de Ciencias Geológicas. 26, 380-394.

Madhavaraju, J. and Ramasamy, S., 1999. Rare earth elements in limestones of Kallankurichchi Formation of Ariyalur Group, Tiruchirapalli Cretaceous, Tamil Nadu. Journal of the Geological Society of India. 54, 291-301.

Medrano, M.D. and Piper, D.Z., 1992. A Normative-Calculation Procedure Used to Determine Mineral Abundances in Rocks from the Montpelier Canyon Section of the Phosphoria Formation, Idaho: A Tool in Deciphering the Minor-Element Geochemistry of Sedimentary Rocks. U.S. Geological Survey Bulletin, 2023, 32pp.

Menezes, A. M. B., 2015. Geology and Characteristic Manganese Ore Deposit at Sambirejo Area, Sawahan Village, Ponjong Subdistrict, Gunungkidul District, Special Region of Yogyakarta (in Indonesian). S.T. Thesis, Unpublished, Gadjah Mada University, Yogyakarta, 159 pp.

Meyer, E.E., Quicksall, A.N., Landis, J.D., Link, P.K., and Bostick, B.C., 2012. Trace and rare earth elemental investigation of a Sturtian cap carbonate, Pocatello, Idaho: evidence for ocean redox conditions before and during carbonate deposition. Precambrian Research, 192 - 195 , p.89-106. DOI:10.1016/j.precamres.2011.09.015

Morse, J.W. and Mackenzie, F.T., 1990. Geochemistry of Sedimentary Carbonates. Elsevier, New York, p.707. DOI:10.1016/S0070-4571(08)70329-7

Mukti, M. M., Siregar, M. S., Praptisih and Supriatna, N., 2005. Carbonate Depositional Environment and Platform Morphology of the Wonosari Formation in the Area East of Pacitan. RISET - Geologi dan Pertambangan. 15(2), 29-38. DOI:10.14203/risetgeotam2005.v15.193

Murray, R.W., Ten Brink, M.R.B., Gerlach, D.C., Russ III, G.P., and Jones, D.L., 1991. Rare earth, major, and trace elements in chertfrom the Franciscan complex and Monterey Group, California Assessing REE sources to fine grained marine sediments. Geochimica et Cosmochimica Acta, 55 (7), p.1875-1895. DOI:10.1016/0016-7037(91)90030-9

Nagendra, R. and Nagarajan, R., 2003. Geochemical studies of Shahabad limestone (Younger Proterozoic), Bhima Basin, Karnataka. Indian Mineralogist. 36(1), 13-23.

Nath, B.N., Roelandts, I., Sudhakar, M., and Plueger, W.L., 1992. Rare earth element patterns of the Central Indian Basin sediments related to their lithology. Geophysical Research Letters. 19, 1197-1200. DOI:10.1029/92GL01243

Neumeister, S., Algeo, T. J., Bechtel, A., Gawlick, H.J., Gratzer, R., and Sachsenhofer, R.F., 2016. Redox conditions and depositional environment of the Lower Jurassic Bächental bituminous marls (Tyrol, Austria). Austrian Journal of Earth Sciences, 109 (2), p.142-159. DOI:10.17738/ajes.2016.0010

Nothdurft, L.D., Webb, G.E. and Kamber, B.S., 2004. Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: Confirmation of seawater REE proxy in ancient limestones. Geochimica et Cosmochimica Acta. 68, 263-283. DOI:10.1016/S0016-7037(03)00422-8

Piepgras, D.J. and Jacobsen, S.B., 1992. The behaviour of rare earth elements in seawater: precise determination of variations in the North Pacific water column. Geochimica et Cosmochimica Acta, 56 (5), p.1851-1862. DOI:10.1016/0016-7037(92)90315-A

Piper, D.Z. and Calvert, S.E., 2009. A marine biogeochemical perspective on black shale deposition. Earth Science Reviews, 95 (1-2), p.63-96. DOI:10.1016/j.earscirev.2009.03.001

Premonowati, Prastistho, B. and Firdaus, I. M., 2012. Allostartigraphy of Punung Paleoreef based on Lithofacies Distibutions, Jlubang Area, Pacitan Region-East Java. Indonesian Journal of Geology. 7(1), 113-122. DOI:10.17014/ijog.v7i2.140

Schieber, J., 1988. Redistribution of rare-earth elements during diagenesis of carbonate rocks from the Mid-Proterozoic Newland Formation, Montana, USA. Chemical Geology, 69 (1-2), p.111-126. DOI:10.1016/0009-2541(88)90163-5

Sholkovitz, E.R., 1990. Rare earth elements in marine sediments and geochemical standards. Chemical Geology, 88 (3-5), p.333-347. DOI:10.1016/0009-2541(90)90097-Q

Siregar, M. S., Kamtono, Praptisih and Mukti, M. M., 2004. Reef Facies of the Wonosari Formation, South of Central Java. RISET - Geologi dan Pertambangan. 14(1), 1-17.

Surono, Toha, B. and Sudarno, I., 1992. Geological Map of the Surakarta-Giritontro Quadrangles, Jawa, 1408-3 & 1407-6 Quadrangles, Scale 1:100.000. Research Center and Geology Development. Department of Mining and Energy.

Titisari, A. D. and Atmoko, D. D., 2015. Genesis of Ponjong pink limestone, Gunungkidul, Special Region of Yogyakarta – Indonesia (in Indonesian). Proceeding Seminar Nasional Kebumian ke-8 Jurusan Teknik Geologi, Fakultas Teknik, UGM. October 15-16, 2015. Indonesia.

Toha, B., Purtyasti, R. D., Srijono, Soetoto, Rahardjo, W. and Pramumijoyo, S., 1994. Geology of Southern Mountain Area: A Contribution (in Indonesian). Geology and Geotechnic Java Island, Since Late Mesozoic to Quarter. 19-36.

Tostevin, R., Shields, G.A., Tarbuck, G.M., He, T., Clarkson, M.O., Wood, R.A., 2016. Effective use of cerium anomalies as a redox proxy in carbonate-dominated marine settings. Chemical Geology, 438, p.146-162. DOI:10.1016/j.chemgeo.2016.06.027

Tribovillard, N., Algeo, T.J., Lyons, T., and Riboulleau, A., 2006. Trace metals as paleoredox and paleoproductivity proxies: An update. Chemical Geology, 232 (1-2), p.12-32. DOI:10.1016/j.chemgeo.2006.02.012

Turekian, K.K., 1972. Chemistry of the earth. Holf, Rinechart and Winston, New York, NY. 131pp.

Wedepohl, K.H., 1978. Manganese: abundance in common sediments and sedimentary rocks. Handbook of Geochemistry v. II/3 (Wedepohl, K.H., ed), 1-17, Springer.

Wignall, P.B. and Myers, K.J., 1988. Interpreting the benthic oxygen levels in mudrocks, a new approach. Geology. 16, 452-455. DOI:10.1130/0091-7613(1988)016<0452:IBOLIM>2.3.CO;2

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